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Issue 28, 2020
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Planar chiral palladacycle precatalysts for asymmetric synthesis

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Abstract

Chiral non-racemic palladacycles were employed as precatalysts for Pd(0) mediated asymmetric synthesis. Addition of HPAr2/base to a ferrocenyloxazoline planar chiral palladacycle resulted in ligand synthesis and palladium capture to give a bidentate Phosferrox/Pd(0) complex. A series of these complexes were generated in situ and applied successfully as catalysts for asymmetric allylic alkylation.

Graphical abstract: Planar chiral palladacycle precatalysts for asymmetric synthesis

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Article information


Submitted
30 Apr 2020
Accepted
02 Jul 2020
First published
02 Jul 2020

This article is Open Access

Org. Biomol. Chem., 2020,18, 5466-5472
Article type
Paper

Planar chiral palladacycle precatalysts for asymmetric synthesis

R. A. Arthurs, D. L. Hughes and C. J. Richards, Org. Biomol. Chem., 2020, 18, 5466
DOI: 10.1039/D0OB01331E

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