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Issue 25, 2019
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Copper-catalyzed regiodivergent 1,4- and 1,6-conjugate silyl addition to diendioates: access to functionalized allylsilanes

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Abstract

A copper-catalyzed regioselective 1,4- and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4- and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

Graphical abstract: Copper-catalyzed regiodivergent 1,4- and 1,6-conjugate silyl addition to diendioates: access to functionalized allylsilanes

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Publication details

The article was received on 13 May 2019, accepted on 23 May 2019 and first published on 25 May 2019


Article type: Communication
DOI: 10.1039/C9OB01086F
Org. Biomol. Chem., 2019,17, 6122-6126

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    Copper-catalyzed regiodivergent 1,4- and 1,6-conjugate silyl addition to diendioates: access to functionalized allylsilanes

    T. Ahmad, Q. Li, S. Qiu, J. Xu, Y. Xu and T. Loh, Org. Biomol. Chem., 2019, 17, 6122
    DOI: 10.1039/C9OB01086F

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