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Issue 7, 2019
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Organocatalytic asymmetric Michael/hemiketalization/acyl transfer reaction of 1,3-propanediones with (E)-2-(2-nitrovinyl)phenols

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Abstract

An organocatalytic asymmetric cascade Michael/hemiketalization/acyl transfer reaction between (E)-2-(2-nitrovinyl)phenols and 1,3-propanediones is disclosed. A cinchona alkaloid derived bifunctional thiourea catalyst was found to be the most effective for this reaction and provided the desired products in moderate to good yields with good to high enantioselectivities.

Graphical abstract: Organocatalytic asymmetric Michael/hemiketalization/acyl transfer reaction of 1,3-propanediones with (E)-2-(2-nitrovinyl)phenols

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Publication details

The article was received on 23 Jul 2018, accepted on 10 Sep 2018 and first published on 10 Sep 2018


Article type: Communication
DOI: 10.1039/C8OB01771A
Org. Biomol. Chem., 2019,17, 1718-1721

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    Organocatalytic asymmetric Michael/hemiketalization/acyl transfer reaction of 1,3-propanediones with (E)-2-(2-nitrovinyl)phenols

    N. Bania and S. C. Pan, Org. Biomol. Chem., 2019, 17, 1718
    DOI: 10.1039/C8OB01771A

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