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Issue 42, 2018
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Iron(III)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines

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Abstract

A Fe-catalyzed highly regioselective α,β-difunctionalization of vinylarenes with diphenylphosphine oxides and anilines is disclosed, in which α,β-aminophosphinoylation is efficiently and conveniently constructed under mild conditions with good functional compatibility and a broad substrate scope. The control experiments have revealed a radical reaction pathway.

Graphical abstract: Iron(iii)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines

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Publication details

The article was received on 31 Aug 2018, accepted on 10 Oct 2018 and first published on 15 Oct 2018


Article type: Communication
DOI: 10.1039/C8OB02151A
Citation: Org. Biomol. Chem., 2018,16, 7782-7786

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    Iron(III)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines

    Y. Wang, W. Wang, R. Tang, Z. Liu, W. Tao and Z. Fang, Org. Biomol. Chem., 2018, 16, 7782
    DOI: 10.1039/C8OB02151A

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