Issue 38, 2018
From the journal:

Organic & Biomolecular Chemistry

Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes†

Joshua A. Homera  and  Jonathan Sperry ORCID logo *a  

* Corresponding authors

a School of Chemical Sciences, 23 Symonds Street, University of Auckland, Auckland, New Zealand
E-mail: j.sperry@auckland.ac.nz

Abstract

A synthesis of the unique bisindole framework present in the mushroom-derived alkaloid sciodole has been achieved, validating a biosynthesis proposal that the C–N bisindole bond present in the natural product is forged by amination of an azafulvenium.

Graphical abstract: Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

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Article information

DOI
https://doi.org/10.1039/C8OB02142B
Article type
Communication
Submitted
31 Aug 2018
Accepted
13 Sep 2018
First published
14 Sep 2018
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2018,16, 6882-6885

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Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes

J. A. Homer and J. Sperry, Org. Biomol. Chem., 2018, 16, 6882 DOI: 10.1039/C8OB02142B

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