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Issue 40, 2018
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An alternative route for the synthesis of hydroxylated pillar[5]arene-based amphiphiles

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Abstract

Conformational mobilities of the units and host–guest complexation with n-octyltrimethylammonium hexafluorophosphate of the synthesized perbenzylated pillar[5]arenes were studied. The formed complex was confirmed by proton nuclear magnetic resonance spectroscopy and mass spectral analysis. Hydroxylated pillar[5]arene-based amphiphiles were synthesized by a co-cyclization strategy followed by catalytic hydrogenation. This approach unlocks the synthesis and the design of a wide range of structural manipulations to these amphiphilic pillararenes.

Graphical abstract: An alternative route for the synthesis of hydroxylated pillar[5]arene-based amphiphiles

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Article information


Submitted
23 Aug 2018
Accepted
26 Sep 2018
First published
26 Sep 2018

Org. Biomol. Chem., 2018,16, 7513-7517
Article type
Paper

An alternative route for the synthesis of hydroxylated pillar[5]arene-based amphiphiles

T. F. Al-Azemi, M. Vinodh, F. H. Alipour and A. A. Mohamod, Org. Biomol. Chem., 2018, 16, 7513
DOI: 10.1039/C8OB02074D

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