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Issue 32, 2018
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E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

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Abstract

An efficient and highly E-selective protocol for the synthesis of vinyl sulfones is described. This simple protocol demonstrates the first synthesis of vinyl sulfones via a silver-catalyzed C–S bond coupling reaction. In addition, the success of the reaction was found to be critically dependent on the use of TEMPO as the additive.

Graphical abstract: E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

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Supplementary files

Article information


Submitted
26 Jun 2018
Accepted
18 Jul 2018
First published
19 Jul 2018

Org. Biomol. Chem., 2018,16, 5748-5751
Article type
Communication

E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

Q. Gui, K. Han, Z. Liu, Z. Su, X. He, H. Jiang, B. Tian and Y. Li, Org. Biomol. Chem., 2018, 16, 5748
DOI: 10.1039/C8OB01502C

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