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Issue 9, 2018

Copper(ii)-mediated, carbon degradation-based amidation of phenylacetic acids toward N-substituted benzamides

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Abstract

The unprecedented synthesis of N-aryl substituted benzamides via the assembly of primary amines and phenylacetic acids has been developed in the presence of copper(II) acetate. This tandem transformation involving carbon–carbon bond cleavage provides a complementary tool with particular application in the synthesis of secondary benzamides.

Graphical abstract: Copper(ii)-mediated, carbon degradation-based amidation of phenylacetic acids toward N-substituted benzamides

Supplementary files

Article information


Submitted
09 Jan 2018
Accepted
02 Feb 2018
First published
02 Feb 2018

Org. Biomol. Chem., 2018,16, 1552-1556
Article type
Paper

Copper(II)-mediated, carbon degradation-based amidation of phenylacetic acids toward N-substituted benzamides

L. Deng, B. Huang and Y. Liu, Org. Biomol. Chem., 2018, 16, 1552 DOI: 10.1039/C8OB00064F

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