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Issue 15, 2018
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Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

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Abstract

An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.

Graphical abstract: Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

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Article information


Submitted
05 Jan 2018
Accepted
13 Mar 2018
First published
14 Mar 2018

Org. Biomol. Chem., 2018,16, 2619-2622
Article type
Communication

Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration

J. Jiang, Y. Hu, X. Cai, L. Wang, Y. Hu, S. Chen, S. Zhang and Y. Zhang, Org. Biomol. Chem., 2018, 16, 2619
DOI: 10.1039/C8OB00033F

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