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Issue 33, 2017
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Intramolecular cyclopropylmethylation via non-classical carbocations

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Abstract

Cyclopropyl–cyclopropyl rearrangement can be achieved selectively by intramolecular trapping of cyclopropylmethyl carbenium ions with an internal nucleophile. This can be exploited as a useful method for the introduction of a cyclopropyl group into complex molecules using readily accessible disubstituted cyclopropane intermediates.

Graphical abstract: Intramolecular cyclopropylmethylation via non-classical carbocations

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Article information


Submitted
13 Jul 2017
Accepted
01 Aug 2017
First published
07 Aug 2017

Org. Biomol. Chem., 2017,15, 6909-6912
Article type
Communication

Intramolecular cyclopropylmethylation via non-classical carbocations

M. Skvorcova and A. Jirgensons, Org. Biomol. Chem., 2017, 15, 6909
DOI: 10.1039/C7OB01721A

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