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Issue 35, 2017
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Heptafluoroisopropyl diazomethane (i-C3F7CHN2): in situ generation and synthesis of pyrazoles

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Abstract

A novel chemical reagent – heptafluoroisopropyl diazomethane (i-C3F7CHN2) – has been generated in situ in aqueous media. It readily reacts with electron-deficient alkynes towards polyfluorinated pyrazoles that are important in agrochemistry.

Graphical abstract: Heptafluoroisopropyl diazomethane (i-C3F7CHN2): in situ generation and synthesis of pyrazoles

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Supplementary files

Article information


Submitted
29 Jun 2017
Accepted
13 Jul 2017
First published
14 Jul 2017

Org. Biomol. Chem., 2017,15, 7296-7301
Article type
Paper

Heptafluoroisopropyl diazomethane (i-C3F7CHN2): in situ generation and synthesis of pyrazoles

P. K. Mykhailiuk, Org. Biomol. Chem., 2017, 15, 7296
DOI: 10.1039/C7OB01579H

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