Issue 25, 2017

A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

Abstract

A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts can be accessed for glycosylation. Using low temperature NMR spectroscopy, the aforementioned glycosyl adducts were detected.

Graphical abstract: A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

Supplementary files

Article information

Article type
Paper
Submitted
04 Apr 2017
Accepted
31 May 2017
First published
01 Jun 2017

Org. Biomol. Chem., 2017,15, 5345-5356

A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

J. Hu, A. W. Feng, B. Chang, C. Lin and K. T. Mong, Org. Biomol. Chem., 2017, 15, 5345 DOI: 10.1039/C7OB00839B

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