Issue 14, 2017
From the journal:

Organic & Biomolecular Chemistry

Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates†

Shin-ichi Isobe,a   Shou Terasaki,a   Taisyun Hanakawa,a   Shota Mizunoa  and  Motoi Kawatsura ORCID logo *a  

* Corresponding authors

a Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
E-mail: kawatsur@chs.nihon-u.ac.jp

Abstract

We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.

Graphical abstract: Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

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Article information

DOI
https://doi.org/10.1039/C7OB00514H
Article type
Paper
Submitted
01 Mar 2017
Accepted
09 Mar 2017
First published
09 Mar 2017

Org. Biomol. Chem., 2017,15, 2938-2946

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Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

S. Isobe, S. Terasaki, T. Hanakawa, S. Mizuno and M. Kawatsura, Org. Biomol. Chem., 2017, 15, 2938 DOI: 10.1039/C7OB00514H

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