Issue 46, 2016
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed allylation of sulfonyl hydrazides with alkynes to synthesize allylic arylsulfones†

Chuan-Jun Lu,*a   Hong Chen,a   Dong-Kai Chen,a   Hong Wang,a   Zhen-Ping Yang,a   Jianrong Gaoa  and  Hongwei Jin*a  

* Corresponding authors

a College of Chemical Engineering, Zhejiang University of Technology, Chaowang Road 18#, Hangzhou 310014, China
E-mail: luchuanjun@zjut.edu.cn, jhwei828@zjut.edu.cn

Abstract

A novel method for the construction of allyl arylsulfone derivatives was developed by palladium catalyzed allylation of sulfonyl hydrazides with alkynes. A series of structurally diverse allyl arylsulfones can be regioselectively synthesized in high yields under mild conditions.

Graphical abstract: Palladium-catalyzed allylation of sulfonyl hydrazides with alkynes to synthesize allylic arylsulfones

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Article information

DOI
https://doi.org/10.1039/C6OB01929C
Article type
Paper
Submitted
01 Sep 2016
Accepted
28 Oct 2016
First published
28 Oct 2016

Org. Biomol. Chem., 2016,14, 10833-10839

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Palladium-catalyzed allylation of sulfonyl hydrazides with alkynes to synthesize allylic arylsulfones

C. Lu, H. Chen, D. Chen, H. Wang, Z. Yang, J. Gao and H. Jin, Org. Biomol. Chem., 2016, 14, 10833 DOI: 10.1039/C6OB01929C

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