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Issue 39, 2016
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Total synthesis of haliclamide

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A stereoselective approach for the synthesis of haliclamide 1, a marine natural product, has been developed. The notable features of our synthesis include MacMillan cross aldol, Mitsunobu inversion, Yamaguchi–Hirao alkylation, Steglich esterification and macrolactamization reactions and the Corey–Fuchs protocol as the key steps.

Graphical abstract: Total synthesis of haliclamide

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Article information

15 Aug 2016
02 Sep 2016
First published
02 Sep 2016

Org. Biomol. Chem., 2016,14, 9287-9293
Article type

Total synthesis of haliclamide

S. Gahalawat and S. K. Pandey, Org. Biomol. Chem., 2016, 14, 9287
DOI: 10.1039/C6OB01775D

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