Issue 36, 2016

Iodine-mediated regioselective synthesis of vinyl triflones from styrenes with CF3SO2Na

Abstract

An unexpected regioselective synthesis of vinyl triflones was developed. This iodine-mediated C–H triflylation of styrenes with CF3SO2Na occurred at room temperature affording various vinyl triflones, which could be used for the preparation of other CF3SO2-containing compounds.

Graphical abstract: Iodine-mediated regioselective synthesis of vinyl triflones from styrenes with CF3SO2Na

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2016
Accepted
12 Aug 2016
First published
12 Aug 2016

Org. Biomol. Chem., 2016,14, 8443-8447

Iodine-mediated regioselective synthesis of vinyl triflones from styrenes with CF3SO2Na

L. Hua, H. Li, F. Qing, Y. Huang and X. Xu, Org. Biomol. Chem., 2016, 14, 8443 DOI: 10.1039/C6OB01567K

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