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Issue 34, 2016
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Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

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Abstract

We have developed Pd-catalyzed intermolecular Friedel–Crafts-type allylic alkylation and allylic dearomatization reactions of substituted indoles bearing a nucleophilic group with vinyloxirane, providing an efficient method to synthesize structurally diverse tetrahydrocarboline and spiroindolenine derivatives under mild conditions.

Graphical abstract: Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

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Supplementary files

Article information


Submitted
18 Jul 2016
Accepted
04 Aug 2016
First published
04 Aug 2016

This article is Open Access

Org. Biomol. Chem., 2016,14, 8044-8046
Article type
Communication

Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

R. Gao, Q. Xu, L. Dai and S. You, Org. Biomol. Chem., 2016, 14, 8044
DOI: 10.1039/C6OB01523A

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