Issue 11, 2016
From the journal:

Organic & Biomolecular Chemistry

Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas†

Wenju Chang,‡a   Jingfu Li,‡a   Wenlong Rena  and  Yian Shi*abc  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

b Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

c Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA
E-mail: Yian.Shi@colostate.edu

Abstract

Effective Pd-catalyzed regioselective hydroesterification of 2-allylphenols with phenyl formate is described. A variety of seven-membered lactones can be obtained in good yields under mild conditions without the use of toxic CO gas.

Graphical abstract: Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas

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Article information

DOI
https://doi.org/10.1039/C5OB02663F
Article type
Paper
Submitted
28 Dec 2015
Accepted
26 Jan 2016
First published
26 Jan 2016

Org. Biomol. Chem., 2016,14, 3047-3052

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Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas

W. Chang, J. Li, W. Ren and Y. Shi, Org. Biomol. Chem., 2016, 14, 3047 DOI: 10.1039/C5OB02663F

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