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Issue 1, 2016
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Synthesis of two distinct pyrrole moiety-containing arenes from nitroanilines using Paal–Knorr followed by an indium-mediated reaction

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Abstract

Synthesis of arenes substituted with two differently substituted-pyrrole moieties was investigated. A Paal–Knorr condensation reaction of nitroanilines with 1,4-diketone to nitrophenyl-1H-pyrroles followed by an indium-mediated reduction-triggered coupling reaction with another kind of 1,4-diketone resulted in two distinct pyrrole-containing arenes, variously substituted 1-((1H-pyrrol-1-yl)phenyl)-1H-pyrroles, in reasonable yield.

Graphical abstract: Synthesis of two distinct pyrrole moiety-containing arenes from nitroanilines using Paal–Knorr followed by an indium-mediated reaction

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Supplementary files

Article information


Submitted
09 Oct 2015
Accepted
11 Nov 2015
First published
12 Nov 2015

Org. Biomol. Chem., 2016,14, 265-276
Article type
Paper
Author version available

Synthesis of two distinct pyrrole moiety-containing arenes from nitroanilines using Paal–Knorr followed by an indium-mediated reaction

B. H. Kim, S. Bae, A. Go, H. Lee, C. Gong and B. M. Lee, Org. Biomol. Chem., 2016, 14, 265
DOI: 10.1039/C5OB02101D

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