Issue 43, 2015
From the journal:

Organic & Biomolecular Chemistry

The N-silylation of sulfoximines†

Haibo Peng,a   Jin-Tao Yu,a   Weijie Bao,a   Jinwei Xua  and  Jiang Cheng*a  

* Corresponding authors

a School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou 213164, P. R. China
E-mail: jiangcheng@cczu.edu.cn

Abstract

The copper-catalyzed N-silylation of sulfoximines was achieved in the presence of di-tert-butyl peroxide. Notably, alkyl, phenyl and alkoxyl silanes were all suitable reaction partners. Mechanistic studies revealed that N-silyl acetamide serves as the intermediate.

Graphical abstract: The N-silylation of sulfoximines

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Article information

DOI
https://doi.org/10.1039/C5OB01705J
Article type
Communication
Submitted
13 Aug 2015
Accepted
25 Sep 2015
First published
25 Sep 2015

Org. Biomol. Chem., 2015,13, 10600-10603

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The N-silylation of sulfoximines

H. Peng, J. Yu, W. Bao, J. Xu and J. Cheng, Org. Biomol. Chem., 2015, 13, 10600 DOI: 10.1039/C5OB01705J

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