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Issue 39, 2015
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Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

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Abstract

The potential of TBHP to promote oxidative hydroxylation of α-hydroxy-β-oxophosphonates (HOPs) through C(CO)–C bond cleavage is described. This cleavage, as depicted in the mechanism is expected through an isomer of HOP that reacts with TBHP to generate acids.

Graphical abstract: Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

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Supplementary files

Article information


Submitted
03 Aug 2015
Accepted
03 Sep 2015
First published
03 Sep 2015

Org. Biomol. Chem., 2015,13, 9953-9956
Article type
Communication
Author version available

Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

S. Battula, A. Kumar and Q. N. Ahmed, Org. Biomol. Chem., 2015, 13, 9953
DOI: 10.1039/C5OB01615K

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