Issue 8, 2015

Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

Abstract

A novel copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization to construct allylic thioethers is first demonstrated. Different 1,1-disubstituted olefins could cross-couple with thioethers to generate the corresponding alkenylation products in moderate to excellent yields. This reaction is supposed to proceed via a radical process.

Graphical abstract: Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

Supplementary files

Article information

Article type
Communication
Submitted
08 Dec 2014
Accepted
22 Dec 2014
First published
22 Dec 2014

Org. Biomol. Chem., 2015,13, 2264-2266

Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

H. Cao, D. Liu, C. Liu, X. Hu and A. Lei, Org. Biomol. Chem., 2015, 13, 2264 DOI: 10.1039/C4OB02564D

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