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Issue 6, 2015

Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

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Abstract

A concise and diastereoselective route to the angularly fused [5–6–7] tricyclic carbon framework of the steenkrotin-type diterpenoids was reported. The key features of the strategy are based on an intramolecular nitrile oxide/alkene [3 + 2] cycloaddition and a regio-selective aldol/dehydration sequence.

Graphical abstract: Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

Supplementary files

Article information


Submitted
20 Nov 2014
Accepted
15 Dec 2014
First published
16 Dec 2014

Org. Biomol. Chem., 2015,13, 1643-1646
Article type
Communication

Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

J. Xuan, S. Pan, Y. Zhang, B. Ye and H. Ding, Org. Biomol. Chem., 2015, 13, 1643 DOI: 10.1039/C4OB02439G

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