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Issue 45, 2014
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Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

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Abstract

Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

Graphical abstract: Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

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Supplementary files

Article information


Submitted
26 Sep 2014
Accepted
29 Sep 2014
First published
30 Sep 2014

This article is Open Access

Org. Biomol. Chem., 2014,12, 9180-9183
Article type
Paper
Author version available

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

A. S. Henderson, J. F. Bower and M. C. Galan, Org. Biomol. Chem., 2014, 12, 9180
DOI: 10.1039/C4OB02056A

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