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Issue 42, 2014
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Concise synthesis of 2,4-disubstituted thiazoles from β-azido disulfides and carboxylic acids or anhydrides: asymmetric synthesis of cystothiazole C

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Abstract

A novel and efficient method for the one-pot synthesis of 2,4-disubstituted thiazoles from carboxylic acids or anhydrides is presented. Based on this new method, the total synthesis of the bis-2,4-disubstituted bis(thiazoles) natural product cystothiazole C is also presented.

Graphical abstract: Concise synthesis of 2,4-disubstituted thiazoles from β-azido disulfides and carboxylic acids or anhydrides: asymmetric synthesis of cystothiazole C

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Supplementary files

Article information


Submitted
11 Jul 2014
Accepted
27 Aug 2014
First published
28 Aug 2014

Org. Biomol. Chem., 2014,12, 8453-8461
Article type
Paper

Concise synthesis of 2,4-disubstituted thiazoles from β-azido disulfides and carboxylic acids or anhydrides: asymmetric synthesis of cystothiazole C

Y. Liu, X. Sun, X. Zhang, J. Liu and Y. Du, Org. Biomol. Chem., 2014, 12, 8453 DOI: 10.1039/C4OB01460J

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