Issue 42, 2014
From the journal:

Organic & Biomolecular Chemistry

The first stereoselective total synthesis of neosemburin and isoneosemburin†

Gadi Madhusudhan Reddya  and  Perali Ramu Sridhar*a  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Hyderabad, India
E-mail: prssc@uohyd.ernet.in
Fax: +91-4023012460
Tel: +91-4023014823

Abstract

The Claisen rearrangement of sugar derived allyl vinyl ether, Wittig olefination and intramolecular acetalization reactions were used as key steps in the first stereoselective total synthesis of neosemburin and isoneosemburin through the formation of a 3-C-branched sugar precursor as a key intermediate.

Graphical abstract: The first stereoselective total synthesis of neosemburin and isoneosemburin

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Article information

DOI
https://doi.org/10.1039/C4OB01239A
Article type
Paper
Submitted
14 Jun 2014
Accepted
15 Jul 2014
First published
15 Jul 2014

Org. Biomol. Chem., 2014,12, 8408-8414

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The first stereoselective total synthesis of neosemburin and isoneosemburin

G. M. Reddy and P. R. Sridhar, Org. Biomol. Chem., 2014, 12, 8408 DOI: 10.1039/C4OB01239A

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