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Issue 31, 2014
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C3-Symmetric chiral trisimidazoline-catalyzed Friedel–Crafts (FC)-type reaction

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Abstract

Imidazoline-catalyzed enantioselective Friedel–Crafts (FC)-type reactions were established using C3-symmetric chiral trisimidazolines. The imidazoline catalysts promoted the FC-type reaction of aldimines with 2-naphthols to produce the corresponding adducts in high yields with up to 99% ee.

Graphical abstract: C 3-Symmetric chiral trisimidazoline-catalyzed Friedel–Crafts (FC)-type reaction

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Article information


Submitted
06 May 2014
Accepted
19 Jun 2014
First published
20 Jun 2014

Org. Biomol. Chem., 2014,12, 5827-5830
Article type
Communication
Author version available

C 3-Symmetric chiral trisimidazoline-catalyzed Friedel–Crafts (FC)-type reaction

S. Takizawa, S. Hirata, K. Murai, H. Fujioka and H. Sasai, Org. Biomol. Chem., 2014, 12, 5827
DOI: 10.1039/C4OB00925H

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