SCHEDULED MAINTENANCE
An efficient and expeditious DABCO-mediated synthesis of functionalized enamides from alkenes is delineated. The reaction proceeds through an unprecedented cascade involving an Aza-Michael addition/α-bromination/elimination and a Morita–Baylis–Hillman type reaction to generate functionalized enamides in a regio- & stereoselective fashion.
A. M. Lone and B. A. Bhat, Org. Biomol. Chem., 2014, 12, 242 DOI: 10.1039/C3OB41847B
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