Issue 41, 2013
From the journal:

Organic & Biomolecular Chemistry

The ammonium-promoted formylation of indoles by DMSO and H2O†

Haiyang Fei,a   Jintao Yu,a   Yan Jiang,a   Huan Guoa  and  Jiang Cheng*ab  

* Corresponding authors

a School of Petrochemical Engineering, Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou 213164, P. R. China
E-mail: jiangcheng@cczu.edu.cn

b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Abstract

DMSO and H2O is an efficient combination in the NH4OAc-promoted formylation of indole, where DMSO serves as a C1 carbon source. The mechanism study reveals that the procedure involves a usual and unusual Pummerer reaction.

Graphical abstract: The ammonium-promoted formylation of indoles by DMSO and H2O

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Article information

DOI
https://doi.org/10.1039/C3OB41510D
Article type
Communication
Submitted
23 Jul 2013
Accepted
08 Sep 2013
First published
10 Sep 2013

Org. Biomol. Chem., 2013,11, 7092-7095

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The ammonium-promoted formylation of indoles by DMSO and H2O

H. Fei, J. Yu, Y. Jiang, H. Guo and J. Cheng, Org. Biomol. Chem., 2013, 11, 7092 DOI: 10.1039/C3OB41510D

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