Issue 25, 2013
From the journal:

Organic & Biomolecular Chemistry

Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidinechromophore at the periphery†

Aijian Wang,abc   Lingliang Long,a   Suci Meng,a   Xiufen Li,a   Wei Zhao,c   Yinglin Song,d   Marie P. Cifuentes,e   Mark G. Humphreye  and  Chi Zhang*ab  

* Corresponding authors

a China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, Zhenjiang 212013, P. R. China
E-mail: chizhang@ujs.edu.cn
Fax: +86-511-8879-7815
Tel: +86-511-8879-7128

b China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi, P. R. China
E-mail: chizhang@jiangnan.edu.cn

c Molecular Materials Research Center, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

d School of Physical Science and Technology, Soochow University, Suzhou 215006, P. R. China

e Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia

Abstract

A novel porphyrin derivative bearing one D–π–A–π–D pyrimidine chromophore at the periphery was designed, prepared, and studied using the Z-scan technique, the results showing that this compound exhibits enhanced nonlinear optical (NLO) absorption, refraction and optical limiting responses. The significant NLO properties can be ascribed to an effective combination of distinct nonlinear mechanisms.

Graphical abstract: Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidine chromophore at the periphery

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Article information

DOI
https://doi.org/10.1039/C3OB40323H
Article type
Paper
Submitted
14 Feb 2013
Accepted
11 Apr 2013
First published
16 Apr 2013

Org. Biomol. Chem., 2013,11, 4250-4257

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Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidine chromophore at the periphery

A. Wang, L. Long, S. Meng, X. Li, W. Zhao, Y. Song, M. P. Cifuentes, M. G. Humphrey and C. Zhang, Org. Biomol. Chem., 2013, 11, 4250 DOI: 10.1039/C3OB40323H

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