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Issue 15, 2013
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Phthalide: a direct building-block towards P,O and P,N hemilabile ligands. Application in the palladium-catalysed Suzuki–Miyaura cross-coupling of aryl chlorides

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Abstract

The direct synthesis of new hemilabile ligands from the economical, readily available lactone phthalide is described. Pd-complexes of one such ligand were found highly effective in general Suzuki–Miyaura cross-coupling reactions, including deactivated and hindered aryl chlorides.

Graphical abstract: Phthalide: a direct building-block towards P,O and P,N hemilabile ligands. Application in the palladium-catalysed Suzuki–Miyaura cross-coupling of aryl chlorides

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Publication details

The article was received on 29 Jan 2013, accepted on 27 Feb 2013 and first published on 27 Feb 2013


Article type: Communication
DOI: 10.1039/C3OB40198G
Org. Biomol. Chem., 2013,11, 2404-2407

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    Phthalide: a direct building-block towards P,O and P,N hemilabile ligands. Application in the palladium-catalysed Suzuki–Miyaura cross-coupling of aryl chlorides

    J. McNulty and K. Keskar, Org. Biomol. Chem., 2013, 11, 2404
    DOI: 10.1039/C3OB40198G

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