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Issue 9, 2012
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First kinetic evidence for the CH/π and π/π solute–solvent interaction of C60 in the Diels–Alder reaction with cyclohexadiene

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Abstract

The first CH/π solute–solvent interaction of C60 was evidenced by the kinetic solvent effects in the Diels–Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k2 with empirical solvent polarity and basicity parameters, ET(30) and Dπ, respectively.

Graphical abstract: First kinetic evidence for the CH/π and π/π solute–solvent interaction of C60 in the Diels–Alder reaction with cyclohexadiene

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Publication details

The article was received on 18 Oct 2011, accepted on 24 Nov 2011 and first published on 30 Nov 2011


Article type: Communication
DOI: 10.1039/C2OB06748J
Org. Biomol. Chem., 2012,10, 1730-1734

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    First kinetic evidence for the CH/π and π/π solute–solvent interaction of C60 in the Diels–Alder reaction with cyclohexadiene

    T. Oshima, T. Mikie, N. Ikuma and H. Yakuma, Org. Biomol. Chem., 2012, 10, 1730
    DOI: 10.1039/C2OB06748J

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