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Issue 23, 2011

Naphthalene-fused metallo-porphyrins–synthesis and spectroscopy

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Abstract

Oxidative aromatic coupling of meso-substituted porphyrins bearing one electron-rich naphthalene unit has been studied in detail. After thorough optimization of oxidant, naphthalene-fused porphyrins were prepared in high yield without contamination from chlorinated side-products using Fe(ClO4)3·2H2O. Copper and nickel complexes were successfully transformed into π-expanded porphyrins in 40–83% yield.

Graphical abstract: Naphthalene-fused metallo-porphyrins–synthesis and spectroscopy

Supplementary files

Article information


Submitted
28 Jul 2011
Accepted
13 Sep 2011
First published
13 Sep 2011

Org. Biomol. Chem., 2011,9, 8178-8181
Article type
Paper

Naphthalene-fused metallo-porphyrins–synthesis and spectroscopy

J. P. Lewtak, D. Gryko, D. Bao, E. Sebai, O. Vakuliuk, M. Ścigaj and D. T. Gryko, Org. Biomol. Chem., 2011, 9, 8178 DOI: 10.1039/C1OB06281F

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