Issue 19, 2011
From the journal:

Organic & Biomolecular Chemistry

Highly stereoselective synthesis of tetrasubstituted alkenesviahydroamination of alkynes and C–H acetoxylation†

Weibing Liu,*a   Cui Chena  and  Qing Zhanga  

* Corresponding authors

a School of Chemistry and Life Science, Guangdong University of Petrochemical Technology, 139 Guangdu Two Road, P. R. China
E-mail: lwb409@yahoo.com.cn
Fax: +86-668-2923575
Tel: +86-668-2923956

Abstract

A novel reaction including the sequence of hydroamination of alkynes and subsequent oxidative C–H bond functionalization has been developed in the presence of diacetoxyiodobenzene (DIB). The method allows us to synthesize a wide range of tetrasubstituted (E)-alkenes and provides a potential method to construct densely functionalized carbonyl compounds.

Graphical abstract: Highly stereoselective synthesis of tetrasubstituted alkenesviahydroamination of alkynes and C–H acetoxylation

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Article information

DOI
https://doi.org/10.1039/C1OB05958K
Article type
Communication
Submitted
14 Jun 2011
Accepted
13 Jul 2011
First published
13 Jul 2011

Org. Biomol. Chem., 2011,9, 6484-6486

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Highly stereoselective synthesis of tetrasubstituted alkenesviahydroamination of alkynes and C–H acetoxylation

W. Liu, C. Chen and Q. Zhang, Org. Biomol. Chem., 2011, 9, 6484 DOI: 10.1039/C1OB05958K

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