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Issue 15, 2011
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Highly effective chiral phosphorus amidite–olefinligands for palladium-catalyzed asymmetric allylic substitutions

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Abstract

This paper describes the development of a type of novel P–olefin hybrid ligand by the incorporation of terminal olefins onto phosphorus amidite ligands for palladium-catalyzed asymmetric allylic alkylations of indoles and substitutions with amines to give the desired products in 70–97% yield with 91–98% ee.

Graphical abstract: Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

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Supplementary files

Article information


Submitted
23 May 2011
Accepted
14 Jun 2011
First published
14 Jun 2011

Org. Biomol. Chem., 2011,9, 5369-5372
Article type
Communication

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

Z. Liu, Z. Cao and H. Du, Org. Biomol. Chem., 2011, 9, 5369
DOI: 10.1039/C1OB05803G

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