Jump to main content
Jump to site search

Issue 14, 2011
Previous Article Next Article

Mild preparation of functionalized [2.2]paracyclophanes via the Pummerer rearrangement

Author affiliations

Abstract

[2.2]Paracyclophanes, incorporating functional groups in the aliphatic bridges, suitable for elimination to give [2.2]paracyclophanedienes, are synthesized through a novel approach. It relies on a double Pummerer rearrangement on dithiacyclophane precursors, followed by ring contraction through a photochemical sulfur extrusion, and it is compatible with aryl moieties possessing very different electronic properties.

Graphical abstract: Mild preparation of functionalized [2.2]paracyclophanes via the Pummerer rearrangement

Back to tab navigation

Supplementary files

Article information


Submitted
27 Feb 2011
Accepted
31 Mar 2011
First published
31 Mar 2011

Org. Biomol. Chem., 2011,9, 5018-5020
Article type
Communication

Mild preparation of functionalized [2.2]paracyclophanes via the Pummerer rearrangement

M. Montanari, A. Bugana, A. K. Sharma and D. Pasini, Org. Biomol. Chem., 2011, 9, 5018 DOI: 10.1039/C1OB05319A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements