Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 19, 2009
Previous Article Next Article

Single and dual glycoside clustering around calix[4]arene scaffolds via click thiol–ene coupling and azide–alkyne cycloaddition

Author affiliations

Abstract

We present the first synthesis of calix[4]arene-based S-glycoclusters via photoinduced multiple thiol–ene coupling of tetra- and octa-allyl calix[4]arenes with peracetylated glucosyl thiol (67–88% yields). Moreover we describe the dual clustering at the upper and lower rim of a calix[4]arene with two different sugars (galactose and glucose) via sequential copper(I)-catalyzed azide–alkyne cycloaddition and photoinduced thiol–ene coupling.

Graphical abstract: Single and dual glycoside clustering around calix[4]arene scaffolds via click thiol–ene coupling and azide–alkyne cycloaddition

Back to tab navigation

Supplementary files

Publication details

The article was received on 29 Jun 2009, accepted on 20 Jul 2009 and first published on 30 Jul 2009


Article type: Communication
DOI: 10.1039/B912686D
Citation: Org. Biomol. Chem., 2009,7, 3910-3913

  •   Request permissions

    Single and dual glycoside clustering around calix[4]arene scaffolds via click thiol–ene coupling and azide–alkyne cycloaddition

    M. Fiore, A. Chambery, A. Marra and A. Dondoni, Org. Biomol. Chem., 2009, 7, 3910
    DOI: 10.1039/B912686D

Search articles by author

Spotlight

Advertisements