Issue 19, 2009
From the journal:

Organic & Biomolecular Chemistry

Ruthenium-catalyzed selective N,N-diallylation- and N,N,O-triallylation of free amino acids†

Basker Sundararaju,a   Mathieu Achard,a   Gangavaram V. M. Sharmab  and  Christian Bruneau*a  

* Corresponding authors

a UMR6226 CNRS–Université de Rennes, Sciences chimiques de Rennes, Catalyse et Organométalliques, Campus de Beaulieu, Rennes Cedex, France
E-mail: christian.bruneau@univ-rennes1.fr
Fax: +33 223236939
Tel: +33 223236283

b Organic Chemistry Division III, D 211, Discovery Laboratory, Indian Institute of Chemical Technology, Hyderabad, India

Abstract

Selective N,N-diallylation and N,N,O-triallylation of free amino acids in the presence of catalytic amounts of RuCp*(MeCN)3PF6 is reported. The crucial influence of the solvent makes these allylation reactions selectively possible.

Graphical abstract: Ruthenium-catalyzed selective N,N-diallylation- and N,N,O-triallylation of free amino acids

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Article information

DOI
https://doi.org/10.1039/B911097F
Article type
Communication
Submitted
05 Jun 2009
Accepted
21 Jul 2009
First published
31 Jul 2009

Org. Biomol. Chem., 2009,7, 3906-3909

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Ruthenium-catalyzed selective N,N-diallylation- and N,N,O-triallylation of free amino acids

B. Sundararaju, M. Achard, G. V. M. Sharma and C. Bruneau, Org. Biomol. Chem., 2009, 7, 3906 DOI: 10.1039/B911097F

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