Jump to main content
Jump to site search

Issue 6, 2009
Previous Article Next Article

Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator

Author affiliations

Abstract

The synthetic hectorite containing intercalated chiral Δ- and Λ-tris(1,10-phenanthroline)ruthenium(II) ions acts as a heterogeneous chiral catalyst in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde to afford, in combination with asymmetric autocatalytic amplification of enantiomeric excess, 5-pyrimidyl alkanol with high enantiomeric excess.

Graphical abstract: Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator

Back to tab navigation

Article information


Submitted
05 Jan 2009
Accepted
15 Jan 2009
First published
23 Jan 2009

Org. Biomol. Chem., 2009,7, 1073-1075
Article type
Communication

Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator

T. Kawasaki, T. Omine, K. Suzuki, H. Sato, A. Yamagishi and K. Soai, Org. Biomol. Chem., 2009, 7, 1073
DOI: 10.1039/B823282B

Social activity

Search articles by author

Spotlight

Advertisements