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Issue 1, 2009
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Thermal epimerization of diastereomeric Grignard reagents

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Abstract

Thermal epimerization is the key to changing the endo-to-exo ratio of the diastereomeric bornyl and fenchyl Grignard reagents from 67 : 33 to 96 : 4 and from 20 : 80 to 80 : 20, respectively.

Graphical abstract: Thermal epimerization of diastereomeric Grignard reagents

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Publication details

The article was received on 28 Oct 2008, accepted on 30 Oct 2008 and first published on 13 Nov 2008


Article type: Communication
DOI: 10.1039/B819178F
Org. Biomol. Chem., 2009,7, 41-42

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    Thermal epimerization of diastereomeric Grignard reagents

    J. Beckmann and A. Schütrumpf, Org. Biomol. Chem., 2009, 7, 41
    DOI: 10.1039/B819178F

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