Issue 17, 2007
From the journal:

Organic & Biomolecular Chemistry

Palladium catalyzed arylation for the synthesis of polyarenes

Sergio Pascual,a   Paula de Mendozaa  and  Antonio M. Echavarren†*a  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: aechavarren@iciq.es
Fax: (+34) 977920225
Tel: (+34) 977920218

Abstract

We present the current understanding on the mechanism of palladium-catalyzed arylation, which involves a proton abstraction by the base. In addition, we present selected examples of the application of this reaction for the synthesis of large polyarenes to highlight the variety of catalysts and reaction conditions that are currently used.

Graphical abstract: Palladium catalyzed arylation for the synthesis of polyarenes

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Article information

DOI
https://doi.org/10.1039/B707940K
Article type
Emerging Area
Submitted
24 May 2007
Accepted
27 Jun 2007
First published
20 Jul 2007

Org. Biomol. Chem., 2007,5, 2727-2734

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Palladium catalyzed arylation for the synthesis of polyarenes

S. Pascual, P. de Mendoza and A. M. Echavarren, Org. Biomol. Chem., 2007, 5, 2727 DOI: 10.1039/B707940K

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