Issue 2, 2007
From the journal:

Organic & Biomolecular Chemistry

Acyl palladium species in synthesis: single-step synthesis of α,β-unsaturated ketones from acid chlorides†

Russell J. Cox*a  and  Andrew S. Evitta  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: r.j.cox@bris.ac.uk
Fax: +44 (0)117 9298611

Abstract

Conditions are reported for the facile, one-pot synthesis of α,β-unsaturated ketones via the palladium-catalysed cross-coupling of acyl chlorides with hydrozirconated acetylenes, and its use in the 2-step synthesis of D-5-O-benzyl deoxyxylulose.

Graphical abstract: Acyl palladium species in synthesis: single-step synthesis of α,β-unsaturated ketones from acid chlorides

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Article information

DOI
https://doi.org/10.1039/B616582F
Article type
Communication
Submitted
13 Nov 2006
Accepted
24 Nov 2006
First published
05 Dec 2006

Org. Biomol. Chem., 2007,5, 229-232

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Acyl palladium species in synthesis: single-step synthesis of α,β-unsaturated ketones from acid chlorides

R. J. Cox and A. S. Evitt, Org. Biomol. Chem., 2007, 5, 229 DOI: 10.1039/B616582F

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