Issue 11, 2006
From the journal:

Organic & Biomolecular Chemistry

Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f]thiepines

Paul Wyatt,*a   Andrew Hudson,a   Jonathan Charmant,a   A. Guy Orpena  and  Hirihattaya Phetmunga  

* Corresponding authors

a School of Chemistry, Cantock's Close, Bristol, UK

Abstract

Several chiral thiepines were efficiently constructed using sulfur diimidazole in combination with a variety of bislithiated carbon fragments. The sulfur atom in these thiepines is found to be unusually unreactive compared to diphenylsulfide.

Graphical abstract: Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f]thiepines

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Article information

DOI
https://doi.org/10.1039/B516606C
Article type
Paper
Submitted
23 Nov 2005
Accepted
14 Mar 2006
First published
03 May 2006

Org. Biomol. Chem., 2006,4, 2218-2232

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Synthesis and chemistry of enantiomerically pure 10,11-dihydrodibenzo[b,f]thiepines

P. Wyatt, A. Hudson, J. Charmant, A. G. Orpen and H. Phetmung, Org. Biomol. Chem., 2006, 4, 2218 DOI: 10.1039/B516606C

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