Issue 4, 2006
From the journal:

Organic & Biomolecular Chemistry

Supported metalloporphyrincatalysts for alkeneepoxidation

Emilie Bruléa  and  Yolanda R. de Miguel*b  

* Corresponding authors

a Université Pierre et Marie Curie, Paris VI, Laboratoire de synthèse organique et organométallique, Tour 44-45, 1er étage, 4 Place Jussieu, Paris Cedex 05, France

b LABEIN-Tecnalia, Calle Geldo, Edificio 700, Parque Tecnológico de Bizkaia, Derio, Bizkaia, Spain
E-mail: ydemiguel@labein.es
Fax: +34 94 607 3349

Abstract

This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.

Graphical abstract: Supported metalloporphyrin catalysts for alkene epoxidation

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Article information

DOI
https://doi.org/10.1039/B509985D
Article type
Perspective
Submitted
19 Jul 2005
Accepted
23 Nov 2005
First published
20 Dec 2005

Org. Biomol. Chem., 2006,4, 599-609

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Supported metalloporphyrin catalysts for alkene epoxidation

E. Brulé and Y. R. de Miguel, Org. Biomol. Chem., 2006, 4, 599 DOI: 10.1039/B509985D

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