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Issue 16, 2005
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Titanocene(ii)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

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Abstract

Treatment of 1,1-dichloroalk-1-enes with Cp2Ti[P(OEt)3]2 produced organotitanium species, which afford allenes on treatment with aldehydes and ketones.

Graphical abstract: Titanocene(ii)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

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Article information


Submitted
22 Jun 2005
Accepted
24 Jun 2005
First published
11 Jul 2005

Org. Biomol. Chem., 2005,3, 2914-2916
Article type
Communication

Titanocene(II)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

T. Shono, K. Ito, A. Tsubouchi and T. Takeda, Org. Biomol. Chem., 2005, 3, 2914
DOI: 10.1039/B508820H

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