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Issue 3, 2005
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Carbolithiation of gem-aryl disubstituted methylenecyclopropanes

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Abstract

A novel carbolithiation of gem-aryl disubstituted methylenecyclopropanes was disclosed by the treatment with BuLi in THF at −78 °C. The corresponding addition products can be obtained in good to high yields by quenching with various electrophiles.

Graphical abstract: Carbolithiation of gem-aryl disubstituted methylenecyclopropanes

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Supplementary files

Article information


Submitted
11 Nov 2004
Accepted
02 Dec 2004
First published
17 Dec 2004

Org. Biomol. Chem., 2005,3, 399-400
Article type
Communication

Carbolithiation of gem-aryl disubstituted methylenecyclopropanes

J. Huang and M. Shi, Org. Biomol. Chem., 2005, 3, 399
DOI: 10.1039/B417139J

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