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Issue 3, 2005
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Synthesis of sedamine by tethered cyclofunctionalisation

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Abstract

The piperidine alkaloid, (+)-sedamine has been synthesised starting from (S)-1-phenyl-3-butenol using a stereoselective, intramolecular palladium-catalysed cyclocarbonylation reaction of a substituted hydroxylamine.

Graphical abstract: Synthesis of sedamine by tethered cyclofunctionalisation

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Article information


Submitted
05 Oct 2004
Accepted
15 Nov 2004
First published
06 Jan 2005

Org. Biomol. Chem., 2005,3, 520-523
Article type
Paper

Synthesis of sedamine by tethered cyclofunctionalisation

R. W. Bates and J. Boonsombat, Org. Biomol. Chem., 2005, 3, 520 DOI: 10.1039/B415297B

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