Issue 12, 2004
From the journal:

Organic & Biomolecular Chemistry

Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins†

Mark D. Keränena  and  Peter Eilbracht*a  

* Corresponding authors

a Fachbereich Chemie, Organische Chemie I, Universität Dortmund, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany
E-mail: peter.eilbracht@udo.edu
Fax: +49 (0)231 755 5363
Tel: +49 (0)231 755 3857

Abstract

Starting from unsaturated carbonyl compounds a mild new cascade reaction involving enolboration, rhodium-catalysed hydroformylation and intramolecular aldol addition in a regio- and diastereoselective fashion leads to cyclic compounds containing highly-functionalised quaternary carbon centres.

Graphical abstract: Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B405120C
Article type
Communication
Submitted
05 Apr 2004
Accepted
17 May 2004
First published
25 May 2004

Org. Biomol. Chem., 2004,2, 1688-1690

Permissions

Request permissions

Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins

M. D. Keränen and P. Eilbracht, Org. Biomol. Chem., 2004, 2, 1688 DOI: 10.1039/B405120C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements