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Issue 12, 2004
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Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins

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Abstract

Starting from unsaturated carbonyl compounds a mild new cascade reaction involving enolboration, rhodium-catalysed hydroformylation and intramolecular aldol addition in a regio- and diastereoselective fashion leads to cyclic compounds containing highly-functionalised quaternary carbon centres.

Graphical abstract: Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins

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Publication details

The article was received on 05 Apr 2004, accepted on 17 May 2004 and first published on 25 May 2004


Article type: Communication
DOI: 10.1039/B405120C
Org. Biomol. Chem., 2004,2, 1688-1690

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    Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins

    M. D. Keränen and P. Eilbracht, Org. Biomol. Chem., 2004, 2, 1688
    DOI: 10.1039/B405120C

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