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Issue 20, 2003
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A rapid stereocontrolled synthesis of the 3a-hydroxy-pyrrolo[2,3-b]indole skeleton, a building block for 10b-hydroxy-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-diones

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Abstract

A two-step selenocyclisation–oxidative deselenation sequence was used to establish the 3a-hydroxy-pyrrolo[2,3-b]indole core; these tricycles were used as effective precursors to 10b-hydroxy-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-diones.

Graphical abstract: A rapid stereocontrolled synthesis of the 3a-hydroxy-pyrrolo[2,3-b]indole skeleton, a building block for 10b-hydroxy-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-diones

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Publication details

The article was received on 21 Jul 2003, accepted on 08 Sep 2003 and first published on 15 Sep 2003


Article type: Communication
DOI: 10.1039/B308288A
Org. Biomol. Chem., 2003,1, 3492-3494

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    A rapid stereocontrolled synthesis of the 3a-hydroxy-pyrrolo[2,3-b]indole skeleton, a building block for 10b-hydroxy-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-diones

    S. V. Ley, E. Cleator and P. R. Hewitt, Org. Biomol. Chem., 2003, 1, 3492
    DOI: 10.1039/B308288A

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