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Issue 22, 2003
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Highly enantioselective alkaloid synthesis via ene-type cyclizations catalyzed by cationic chiral palladium(ii) complexes of PN-ligands with an achiraloxazoline unit

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Abstract

A highly efficient asymmetric alkaloid synthesis via ene-type cyclizations catalyzed by cationic chiral palladium(II) complexes of PN-ligands with an achiral gem-dimethyl oxazoline unit is shown to give 5-membered products with a quaternary carbon center, including a spiro-amide, almost quantitatively with extremely high enantiomeric excesses.

Graphical abstract: Highly enantioselective alkaloid synthesis via ene-type cyclizations catalyzed by cationic chiral palladium(ii) complexes of PN-ligands with an achiral oxazoline unit

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Publication details

The article was received on 23 May 2003, accepted on 17 Sep 2003 and first published on 26 Sep 2003


Article type: Communication
DOI: 10.1039/B305865B
Org. Biomol. Chem., 2003,1, 3871-3873

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    Highly enantioselective alkaloid synthesis via ene-type cyclizations catalyzed by cationic chiral palladium(II) complexes of PN-ligands with an achiral oxazoline unit

    M. Hatano and K. Mikami, Org. Biomol. Chem., 2003, 1, 3871
    DOI: 10.1039/B305865B

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